The separation of titanium (Ti) (IV) in acidic leach solutions of vanadium slag by solvent extraction with ctyl tertiary amine (N235) is proposed. Because the leach solutions contain a lot of vanadium (V) and iron (Fe) impurities, the effects of various conditions on the separation of Ti, V, and Fe were investigated.
The vanadium and iron distribution ratios were 308 and 0.0064, respectively, and the vanadium-to-iron separation factor was as high as 47956, which indicates that vanadium and iron were efficiently separated from the V-Fe-loaded organic phase by HCl stripping. Table 4. Results of the four-stage countercurrent stripping of vanadium.
Vanadium in vanadium slag existed in the form of FeV 2 O 4.The traditional method is to recycle V from vanadium slag by oxidizing V 3+ to V 5+.In order to recycle V from vanadium slag, the industry mainly adopts calcification roasting and sodium roasting (Xiang et al., 2017; Yue et al., 2020; Wu et al., 2018; Wang et al., 2019c).However, these two processes …
Moreover, D2EHPA revealed a suitable separation for vanadium (IV) over iron (II) by extracting VO+ 2. None of the extractants tested can be used to separate vanadium (V) over iron (II) or vanadium ...
Results showed that vanadium leaching efficiency was 91.07% and iron leaching efficiency decreased from 84% to 23.86% under optimal leaching conditions—H 2 SO 4 -to-H …
The vanadium content of molten iron is an important economic indicator for a vanadium–titanium magnetite smelting blast furnace, and it is of great importance in blast furnace production to be ...
Iron is the main element that affects the purification and enrichment of vanadium solutions. In traditional solvent extraction, only the vanadium is recovered and the iron is lost.Thus, the separation and recovery of vanadium and iron from an oxalic-acid-based shale leachate by coextraction and stepwise stripping was investigated.
We speculate that the proposed separation method for iron, vanadium, and titanium from vanadium-bearing titanomagnetite could represent a new alternative method for the comprehensive utilization of vanadium-bearing ti-tanomagnetite. …
PDF | On May 1, 2023, Jianfa Jing and others published Chromium and iron recovery from hazardous extracted vanadium tailings via direct reduction magnetic separation | Find, read and cite all the ...
The beneficiation of this kind of ore generally uses weak magnetic separation to separate the vanadium iron concentrate, ... etc., and the heavy sand minerals are in a fine-grained state; the gangue is mainly silicate minerals. The combined process of gravity separation, magnetic separation and electric separation is adopted in production. The ...
Vanadium and titanium magnetite ores are being smelted in a blast furnace, and the resulting iron liquid is refined in a converter to produce vanadium slag [1], [2].The vanadium slag undergoes sodium roasting and water leaching to produce an extracted vanadium tailing [3], [4].The total amount of extracted vanadium tailings in China exceeds 0.6 million tons per year [5].
Vanadium is a strategic metal and its compounds are widely used in industry. Vanadium pentoxide (V2O5) is one of the important compounds of vanadium, which is mainly extracted from titanomagnetite ...
The recovery of iron and vanadium is done by Highveld Steel and Vanadium Corp. in South Africa. Steel and vanadium-containing slag are produced, ... For the preparation of the iron-bearing feed material the mined beach sands are upgraded by magnetic separation and gravity methods. A concen- trate containing 52--54% Fe can be produced at high ...
vanadium-bearing metallic iron from vanadium tailings via a semi-molten reduction-magnetic separation method was investigated. The effects of the reductant (carbon) dosage, temperature,
This study focused on vanadium extraction and iron separation from vanadium-bearing shale, involving the coordination of H3PO4 in an H2SO4 leaching system. The effects of the ratio and quantity of ...
Vanadium and chromium are usually oxidized to toxic V(V) and Cr(VI), and there is a lack of direct separation and recovery research on low valence vanadium and chromium; (2) Stepwise separation of vanadium, chromium and iron …
Gas-based reduction roasting magnetic separation process was conducted to separate and recover iron and titanium from oxidized vanadium titano-magnetite (VTM).
The main components of the VTMT are iron (56.39 % Fe 2 O 3), titanium (12.39 % TiO 2), silicon (11.94 % SiO 2), whereas SiO 2 (98.90 % SiO 2) makes up the majority of quartz sand. The high content of iron and titanium in VTMT is beneficial for the preparation of photocatalytic materials, while the SiO 2 in quartz sand aids in forming monolithic ...
process in this study for extraction and separation of vanadium, iron, and titanium using a mixture extractant of P204 and P507 was proposed. The inuences of the P204-P507 concentra-tion, P204 and P507 ratio, initial pH, phase ratio (O/A), and contact time on the extractions of vanadium, iron, and titanium were investigated.
The present process can effectively separate vanadium, titanium, iron, and magnesium and synthesize anhydrite products realizing the cleaner utilization of steel slag.
This project considers the retrieval of vanadium and similar valuable by-products when producing steel from iron sands. This recovery should be optimised without compromising steel production. ... and the effects of the main factors on the extraction of vanadium and iron were investigated. ... a prior separation of TiO 2 as its [Ti(OH)(HND) 3 ...
The comprehensive utilization of iron tailings, a low-grade and refractory iron mineral, has received global attention. Various recovery technologies, including gravity separation [6], flotation [7], magnetic separation [8], and bioleaching [9], have been developed to exploit the rich iron resources in iron tailings based on the distinct properties of iron oxides and gangue …
from iron oxides to metallic iron,[61–66] but few studies on the effect of additives on the component separation effects have been carried out. Furthermore, considering the difference between the present ultra-high-titanium magnetite and other vanadium–titanium magnetite, this special low-grade, high-vanadium, and ultra-high-tita-
Research in our laboratory found that after the new process of roasting pretreatment-ammonium sulfate roasting-acid leaching of vanadium titanomagnetite, vanadium and iron were dissolved in the leaching solution, while titanium was enriched to the leaching residue, achieving the selective separation of vanadium, iron and titanium [6].However, since …
Among selected extractants, Cyanex 923 showed the best selectivity for vanadium (V) over iron (III) by extracting of VO2 SO 4‐ in the system. Moreover, D2EHPA revealed a …
Rare metal vanadium plays an irreplaceable role in the development of emerging industries, national defense and military industry and the upgrading of traditional industries [1], [2].Vanadium products in China account for 80 % of the global vanadium products, and China is the world's largest vanadium production, supply and consume [3].Vanadium shale has the …
separation and milling. As expected for high-energy offshore environments, the low organic matter content ... Iron sand particles size and elutriate copper concentrations were negatively linearly correlated. ... VTM is a black iron ore that comprises vanadium pentoxide (V2O2), titanium oxide
DOI: 10.1007/s11663-023-02958-3 Corpus ID: 266442120; Enhancing Reduction Separation and Efficient Recovery of Iron, Vanadium, and Titanium for Ultra-High-Titanium Magnetite
Based on the speciation analysis of vanadium in sulfuric acid medium, the single-stage extraction efficiency of vanadium, iron, and titanium was 94.21%, 3.45%, and 5.32%, respectively, under the ...