The exact mechanism behind the antibacterial efficacy of nanoparticles remain unexplored till date. This study is aimed at shedding light on the mechanism adopted by magnesium oxide nanoparticles ...
The results point to a barrier layer concept. The oxide layer becomes porous at a critical thickness. Open porosity increases from 0.01% at 10 μm to 3% at 100 μm. Between the outer porous oxide and the metal, a dense interlayer exists. This is only ≤30 nm in nodular oxide but has been found to be several hundred nm in uniform post ...
In the present work, the nucleation rates and radii of cerium oxide inclusions were obtained using classical nucleation theory. The growth of (CeO 2) n and (Ce 2 O 3) n (n = 1–6) clusters based on a two-step nucleation mechanism was assessed and the thermodynamic properties of these clusters and of cerium oxide nanoparticles were examined. In ...
ZIRCONIUM:。。 in a way that uses or relates to the subconscious (= the part of your mind that notices and remembers information when you are not actively trying to do so, and influences your behaviour even though you do not realize it)
The microscopic reaction pathway plays a crucial role in determining the electrochemical performance. However, artificially manipulating the reaction pathway still faces considerable challenges.
The exact mechanisms underlying iron oxide particulate-induced adverse outcomes are poorly understood, but most research suggests they are related to the physicochemical properties of the iron or iron oxide metal compounds, and are largely due to iron oxide-induced or catalyzed oxidative stress.
Here, we investigated the corrosion performance and oxide formation mechanism of the CZ1 alloy and compared it with a related Zr-1Nb-1Sn model alloy. Autoclave experiments of CZ1 and Zr-1Nb-1Sn alloys were performed for up to 820 d, and oxide thickness was measured by focused ion beam (FIB) and scanning electron microscopy (SEM).
In order to get a better understanding of the mechanism governing hydrogen absorption behavior in Zr-based alloys, various characterization techniques were applied to …
The results point to a barrier layer concept. The oxide layer becomes porous at a critical thickness. Open porosity increases from 0.01% at 10 μm to 3% at 100 μm. Between the outer porous oxide and the metal, a dense interlayer exists. This …
Magnesium oxide is a compound commonly used as a laxative for the symptomatic relief of acid indigestion and upset stomach, and in health supplements for cardiovascular and neuromuscular health. ... Mechanism of action. The term "Milk of Magnesia" was first used to describe a white aqueous, mildly alkaline suspension of magnesium hydroxide ...
The method of determination of the oxygen diffusion coefficient in oxide on zirconium alloys and adjacent metal using weight gain and oxide thickness measurement data …
We investigated the reaction mechanism of atomic layer deposition (ALD) of zirconium oxide (ZrO 2) by integrating experiments and calculations.
Therefore, a MgAl-double oxide was prepared by calcining MgAl-LDH and used for U(VI) removal from wastewater/simulated seawater. The effect of experiment conditions (e.g., contact time, initial concentration, pH, coexisting ions and water matrices) were explored. ... According to related studies, the synergistic mechanisms of the co-adsorption ...
Bossis, P, Thomazet, J, & Lefebvre, F. "Study of the Mechanisms Controlling the Oxide Growth Under Irradiation: Characterization of Irradiated Zircaloy-4 and Zr-1Nb-O Oxide Scales." Zirconium in the Nuclear Industry: Thirteenth International Symposium. Ed. Moan, G, & Rudling, P. 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959: ASTM …
In order to develop novel anti-corrosion technologies of metals, the photoelectrochemical cathodic protection (PECCP) coating with zinc indium sulfide/titanium oxide (Zn 2 In 2 S 5 /TiO 2) was successfully fabricated and its enhanced anticorrosion mechanism was explored in marine environment under light and dark condition, respectively.It found that the …
3 Antioxidant stress response mechanism of cerium oxide nanoparticles. Reactive oxygen species (ROS) are essential byproducts of cellular metabolism, including superoxide anion (O 2–), hydrogen peroxide (H 2 O 2), and hydroxyl radical (-OH) . ROS play a crucial role in regulating cellular signaling pathways, which typically control cell ...
Iridium and Titanium oxide are known as the corrosion-resistant and bonding agents for mixed metal oxide coatings. Based on this fact, this study aims to investigate the effect of these oxides on the deactivation mechanisms of a typical Ti/(36RuO 2-xIrO 2-(64-x)TiO 2) in sodium chloride solution.The coating with quantities of 16, 26, and 36 wt. % titanium oxide is …
Antibacterial activity and mechanism of action of zinc oxide nanoparticles against Campylobacter jejuni. Appl. Environ. Microbiol. 77 2325–2331. 10.1128/AEM.02149-10 [PMC free article] [Google Scholar] Zhang J., Liu X. (2002). Study on tetrazolium salt colorimetric assay for growth and survival of bacteria.
The emerging oxide pathway mechanism (OPM) streamlines direct O–O radical coupling, circumventing the formation of oxygen vacancy defects featured in the lattice oxygen mechanism (LOM) and bypassing additional reaction intermediates (*OOH) inherent to the adsorbate evolution mechanism (AEM). With only *O and *OH as intermediates, OPM-driven ...
Here we report the oxide formation mechanism of a CZ1 zirconium alloy with corrosion resistance surpassing many other zirconium alloy systems, such as Zircaloy-4 and Zr-1Nb-1Sn alloys. Autoclave...
Research on ruthenium oxide (RuO 2) catalysts as alternatives to Ir-based catalysts for the acidic oxygen evolution reaction (OER) has focused on enhancing activity and stability by incorporating heteroatoms.However, the relationship between the amount of incorporated heteroatom and the OER mechanism remains unclear.
The mechanism of oxidizing reaction in the preparation of graphene oxide (GO) by a chemical oxidation method remains unclear. The main oxidant of graphite oxide has not been determined. Here, we show a new mechanism in which Mn2O7, the main oxidant, is heated to decompose oxygen atoms and react with graphite. The whole preparation process constitutes …
The interaction between biochar and cobalt oxide resulted in several notable enhancements in the BS-Co 3 O 4 composite. Specifically, there was an ... which contributed to the high efficacy of PMS activation for TC degradation. The activation mechanism of PMS by BS-Co 3 O 4 was elucidated through quenching experiments and electron paramagnetic ...
Download Citation | Amorphous zirconium oxide activates peroxymonosulfate for selective degradation of organic compounds: Performance, mechanisms and structure-activity relationship | Application ...
In order to get a better understanding of the mechanisms governing corrosion of Zr-based alloys, several examinations have been performed on a variety of samples with uniform …
The regulatory mechanisms of cerium oxide nanoparticles in oxidative stress and emerging applications in refractory wound care Lijun Yi1†, Lijian Yu1†, Shouying Chen2,3†, Delong Huang4, Cheng Yang4,5, Hairui Deng2,3, Yiheng Hu6, Hui Wang7, Zan Wen2,3*, Yiren Wang2,3* and Yu Tu8* 1Department of General Surgery, Luzhou People's Hospital, Luzhou, …
The corrosion and oxidation behavior of Zr and some alloys are discussed in terms of the oxide defect structure and the electric conductivity behavior in the oxide. A speculative mechanism …
Here we report the oxide formation mechanism of a CZ1 zirconium alloy with corrosion resistance surpassing many other zirconium alloy systems, such as Zircaloy-4 and Zr-1Nb-1Sn alloys. Autoclave ...
Mass balance criteria are presented for inferring oxide growth mechanisms from the oxygen isotope profile. For the case of inward growing scales, a diffusion model is presented which describes the ...
According to the X-ray diffraction (XRD) data on the molten oxide–fluoride mixtures under study, the reaction of zirconium oxide with the fluoride melts affords fluorozirconates of the …