"The study we have just completed at ANSTO enables us to be increasingly predictive toward REE- extraction and separation process conditions," said Mark Saxon, CEO and President.
ANSTO's Minerals business unit have extensive experience in rare earth process development and piloting, all the way though to separated final products. We provide specialised consulting …
For monazite, sulfuric acid baking at temperatures above 200 °C with an acid to solid ratio in the range of 1: 1 to 2.5: 1 is generally required for complete decomposition of the …
separation, monazite, which is a para magnetic mineral, was found in a non-negligible concentration of 0.57 wt% on average in the medium grade zircon .
The monazite content of the leach residue was 91.2%. Therefore, bastnaesite and monazite in the mixed RE concentrate were effectively separated, and the metallurgical process of bastnaesite was completed simultaneously. Subsequent decomposition of monazite in the leach residue was performed via the NaOH decomposition method.
The mixed rare earth ore at Bayan Obo primarily comprises fluorocerium and monazite, characterized by significant variances in physical and chemical properties, which is difficult to extract. 11 Currently, extraction predominantly involves high-temperature roasting with highly polluting concentrated sulphuric acid. 12 Although this process has made an important …
For the primary separation, a Magnetic Separator (typically an Induced Magnetic Roll or Rare Earth Roll Separator) removes magnetically-susceptible para and ferro magnetic minerals (e.g. ilmenite, garnet, monazite). …
Monazite, a rare earth and thorium phosphate mineral, is one of the major minerals processed for extraction of rare earths . ... in 0.9 M sulfuric acid at 20–25 °C for 2 h. Solid-liquid separation after leaching was by vacuum filtration . Liquors were analysed by inductively-coupled plasma optical emission spectroscopy (ICP-OES) and mass ...
Chemical processing of monazite involves digestion in caustic soda to 'crack' the phosphate matrix, dissolution of the rare earths in acid and their separation by multi-stage solvent extraction usually in mixer-settlers. The processing is complicated by the presence of 4-8 wt% thorium and 0.1-0.3 wt% uranium in the monazite.
Chemical processing of monazite involves digestion in caustic soda to 'crack' the phosphate matrix, dissolution of the rare earths in acid and their separation by multi-stage solvent …
Monazite and rare earth trimetaphosphate (PrP 3 O 9, a cyclic polyphosphate species) were identified in the sample after baking at 800°C (Fig. 2). These phases were also …
The cracked concentrate is then leached to dissolve REE in a solution and subsequently recover those via neutralization, precipitation or solvent extraction methods. This paper reviewed the cracking and leaching methods applied to REE concentrates to produce an intermediate product for further REE separation.
In this study, mineralogical analysis and beneficiation experiments were conducted using a placer deposit of North Korea, on which limited information was available, to confirm the feasibility of development. Rare earth elements (REEs) have vital applications in modern technology and are growing in importance in the fourth industrial revolution. However, the price …
The behavior of actinium-227 and actinium-228 in the life cycle of monazite processing is considered. The recommended system for separation of actinium-227 and actinium-228 is 90– TBP–300–350 g/dm3 of Ln(NO3)3–0.1–0.5 mol/dm3 of HNO3. The process is combined: actinium-227 and actinium-228 are removed simultaneously with purification from …
Magnetic separation of monazite from mixed minerals ... separation step were reprocessed at increasing magnetic field strengths in the order 0.11, 0.29, 0.56, 0.89 and 1.08 T.
Karin Soldenhoff's 18 research works with 546 citations and 2,191 reads, including: Beneficial effect of iron oxide/hydroxide minerals on sulfuric acid baking and leaching of monazite
Two samples of REO-bearing monazite concentrate (-53 µm and -125+53 µm) were submitted to the Minerals Division of ANSTO for natural radioactivity analysis. The monazite concentrates, grading 52.4% TREO for the -53 µm fraction and 66.9% TREO for the -125+53 µm fraction, were produced by gravity
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In this work, the beneficial effect of three iron oxide/hydroxide minerals, namely hematite, goethite and magnetite, added to high grade monazite concentrate in the acid bake (temperature range …
Xenotime is generally found occurring with monazite in placer type deposits at a xenotime-to-monazite weight ratio of 1:200 to 1:20 (Gupta and Krishnamurthy, 2005). Bastnasite is a LREE rich rare earth fluorocarbonate, with a fluoride content in the range of 6.2–8.5%, and a carbonate content of ~20% as CO 2 (Gupta and Krishnamurthy, 2005).
In the sulfuric acid bake, monazite concentrate is mixed with concentrated sulfuric acid and roasted. The rare earth phosphate mineral is converted to rare earth sulfate which dissolves in …
hard-rock monazite ores/concentrates. The chemical reactions in the monazite acid bake can be strongly influenced by the gangue mineralogy of the ore/concentrate. In this work, the beneficial effect of three iron oxide/hydroxide minerals, namely hematite, goethite and magnetite, added to high grade monazite concentrate
The purpose of this research was to study the effectiveness of thorium and uranium separation technique in monazite and xenotime via alkaline fusion method as well as to determine the suitability of this method towards the two minerals. The alkaline fusion process required the minerals to be fused in sodium hydroxide pellet at 300 - 350°C for ...
processes occurring during sulfuric acid baking of a monazite concentrate between 200 and 800°C. The effects of these reactions on the leachability of the rare earths, thorium and …
Most of the monazite grains are reversible negative and are attracted towards the positively charged static electrode. Using wet gravity concentration, both low and high intensity magnetic separation, and electrostatic separation techniques, a high grade concentrate assaying 97 wt. % monazite with a recovery of 76.8% can be obtained.
Using a magnetic separation method at various magnetic intensities, paramagnetic minerals, ilmenite (0.8 T magnetic product), and monazite/xenotime (1.0–1.4 T magnetic product) were recovered ...
An alternative procedure for the processing of monazite mineral concentrate has been suggested. This procedure is based on a prior separation of the REEs and Th oxalates from the sulfate liquor of ...
Magnetic separation at 1.5 teslas intensity resulted in the recovery of 94.8% of the monazite from the MGZS. Gravity separation also recovered 76.6% of the monazite from the MGZS. The combination of these two treatment methods can thus produce three concentrates from MGZS (a monazite concentrate, a zircon concentrate, and a titanium oxide concen-
Systematic study for thermal decomposition of monazite to remove phosphate as a valuable product using Na 2 CO 3 and NaOH roasting processes to validate the TG/DTA studies is reported here. Monazite in 1:1 wt. ratio with Na 2 CO 3 and NaOH requires a temperature of 900 °C and 400 °C, respectively, for 120 min in order to achieve complete conversion of rare …
monazite must be separated to be used. This study aims to determine the effect of pH variations in the separation of components in monazite with multilevel precipitation and determine elements produced from each pH variation. The variation pH starts from pH 0,5 to 10 with a different pH of zero points five. The elements in